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Author(s):   Sivaramakrishnan, R.; Michael, J.V.; Klippenstein, S.J.
Title:   Direct Observation of Roaming Radicals in the Thermal Decomposition of Acetaldehyde
Journal:   J. Phys. Chem. A
Volume:   114
Page(s):   755 - 764
Year:   2010
Reference type:   Journal article
Squib:   2010SIV/MIC755-764

Reaction:   CH3CHO + CO + H2 + ·CH3
Reaction order:   2
Temperature:   1085 - 1415 K
Pressure:  1.45E-2 - 4.13E-2 bar
Rate expression:   no rate data available
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Individual rate constant values are reported in tables. No Arrhenius expression is derived.

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