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Author(s):   Smirnov, V.N.
Title:   Thermal dissociation of chromium hexacarbonyl and its decomposition products-Unsaturated carbonyls
Journal:   Russ. J. Phys. Chem. B
Volume:   4
Page(s):   423 - 427
Year:   2010
Reference type:   Journal article
Squib:   2010SMI423-427

Reaction:   Cr(CO)6CO + Cr(CO)5
Reaction order:   1
Temperature:   600 - 710 K
Pressure:  1.81E13 bar
Rate expression:   no rate data available
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   In real time
Analytical technique:   Vis-UV absorption
Comments:   Rate constants were determined for a range of temperatures; however, no Arrhenius expression is given for the k(T) dependence. Instead, rate constants for individual temperatures are presented in a graphical format.

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