Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Trevitt, A.J.; Goulay, F.; Taatjes, C.A.; Osborn, D.L.; Leone, S.R.
Title:   Reactions of the CN Radical with Benzene and Toluene: Product Detection and Low-Temperature Kinetics
Journal:   J. Phys. Chem. A
Volume:   114
Page(s):   1749 - 1755
Year:   2010
Reference type:   Journal article
Squib:   2010TRE/GOU1749-1755

Reaction:   CN + Toluene → Products
Reaction order:   2
Temperature:   105 K
Pressure:  2.40E11 bar
Rate expression:   1.3x10-10 [±3.0x10-11 cm3/molecule s]
Uncertainty:   1.20000005
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Laval nozzle
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Error bars of 20% are ascribed to the measured rate coefficients to take into account statistical and systematic uncertainties. The only product detected in separate VUV photoionization mass spectrometry experiments is cyanotoluene, NCC6H4CH3.

View full bibliographic record.