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Author(s):   Yasunaga, K.; Gillespie, F.; Simmie, J.M.; Curran, H.J.; Kuraguchi, Y.; Hoshikawa, H.; Yamane, M.; Hidaka, Y.
Title:   A Multiple Shock Tube and Chemical Kinetic Modeling Study of Diethyl Ether Pyrolysis and Oxidation
Journal:   J. Phys. Chem. A
Volume:   114
Page(s):   9098 - 9109
Year:   2010
Reference type:   Journal article
Squib:   2010YAS/GIL9098-9109

Reaction:   C2H5OCH2(·) → CH2O + ·C2H5
Reaction order:   1
Temperature:   900 - 1900 K
Rate expression:   7.07x1014 [s-1] (T/298 K)-0.27 e-54965 [J/mole]/RT
Category:  Theory
Data type:   Derived from detailed balance/reverse rate
Pressure dependence:   Rate constant is high pressure limit
Comments:   Rate constants were estimated based on the values for the reverse reaction.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
900 3.38E11
1000 6.86E11
1100 1.22E12
1200 1.96E12
1300 2.94E12
1400 4.14E12
1500 5.57E12
1600 7.21E12
1700 9.04E12
1800 1.10E13
1900 1.32E13