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Accessibility information
Author(s):   Awan, I.A.; Burgess, D.R.; Manion, J.A.;
Title:   Pressure Dependence and Branching Ratios in the Decomposition of 1-Pentyl Radicals: Shock Tube Experiments and Master Equation Modeling
Journal:   J. Phys. Chem. A
Volume:   116
Page(s):   2895 - 2910
Year:   2012
Reference type:   Journal article
Squib:   2012AWA/BUR2895-2910

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2012AWA/BUR2895-2910   n-C5H11I → Products  881 - 1001   9.12E13       2.04E05      1
  2012AWA/BUR2895-2910   n-C5H11I1-C5H10 + HI  881 - 1001   1.05E13       1.98E05      1
  2012AWA/BUR2895-2910   n-C5H11I1-C5H11 + I  881 - 1001   8.71E13       2.06E05      1
  2012AWA/BUR2895-2910   n-C6H13I → Products  875 - 1011   5.01E13       1.98E05      1
  2012AWA/BUR2895-2910   n-C6H13I1-C6H12 + HI  875 - 1011   8.13E12       1.95E05      1
  2012AWA/BUR2895-2910   n-C6H13I1-hexyl radical + I  875 - 1011   4.27E13       1.99E05      1
  2012AWA/BUR2895-2910   1-C5H11C2H4 + 1-C3H7  400 - 1900   2.00E13   0.35   1.20E05      1
  2012AWA/BUR2895-2910   CH3CH2CH2CH(·)CH3CH3CH=CH2 + ·C2H5  400 - 1900   1.95E13   0.27   1.22E05      1
  2012AWA/BUR2895-2910   3-C5H111-C4H8 + ·CH3  400 - 1900   5.89E12   0.91   1.26E05      1
  2012AWA/BUR2895-2910   CH3CH2CH2CH(·)CH32-(E)-C5H10 +   400 - 1900   1.23E12   1.21   1.43E05      1
  2012AWA/BUR2895-2910   CH3CH2CH2CH(·)CH32-(Z)-C5H10 +   400 - 1900   2.04E12   1.04   1.49E05      1
  2012AWA/BUR2895-2910   1-C5H11CH3CH2CH2CH(·)CH3  400 - 1900   3.72E08   3.03   6.40E04      1
  2012AWA/BUR2895-2910   CH3CH2CH2CH(·)CH31-C5H11  400 - 1900   1.32E08   3.53   7.53E04      1
  2012AWA/BUR2895-2910   1-C5H11 → 3-C5H11  400 - 1900   3.39E05   6.84   7.85E04      1
  2012AWA/BUR2895-2910   3-C5H111-C5H11  400 - 1900   1.26E05   7.51   8.93E04      1
  2012AWA/BUR2895-2910   C2H4 + 1-C3H71-C5H11  400 - 1900   4.90E-15   2.87   2.16E04      2
  2012AWA/BUR2895-2910   CH3CH=CH2 + ·C2H5CH3CH2CH2CH(·)CH3  400 - 1900   5.89E-15   2.48   2.45E04      2
  2012AWA/BUR2895-2910   1-C4H8 + ·CH3 → 3-C5H11  400 - 1900   1.69E-14   2.37   2.18E04      2
  2012AWA/BUR2895-2910   2-(E)-C5H10 + CH3CH2CH2CH(·)CH3  400 - 1900   2.57E-12   1.50   2361      2
  2012AWA/BUR2895-2910   2-(Z)-C5H10 + CH3CH2CH2CH(·)CH3  400 - 1900   2.46E-12   1.60   3642      2

Search returned 20 records.