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Title: Pressure Dependence and Branching Ratios in the Decomposition of 1-Pentyl Radicals: Shock Tube Experiments and Master Equation Modeling
Journal: J. Phys. Chem. A
Volume: 116
Page(s): 2895 - 2910
Year: 2012
Reference type: Journal article
Squib: 2012AWA/BUR2895-2910
Reaction:
n-C5H11I → 1-C5H11 + I
Reaction order:
1
Temperature:
881 - 1001
K
Pressure: 0.80 - 6.00 bar
Rate expression:
8.71x1013 [±1.56x1013 s-1] e-205675 [±1413 J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Pressure dependence:
Rate constant is pressure independent
Experimental procedure:
Shock tube
Excitation technique:
Thermal
Time resolution:
By end product analysis
Analytical technique:
GC-MS
Comments:
Uncertainties are one standard error as derived from the least squares analysis.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 881 | 5.57E1 |
| 900 | 1.01E2 |
| 925 | 2.12E2 |
| 950 | 4.28E2 |
| 975 | 8.34E2 |
| 1000 | 1.57E3 |
| 1001 | 1.61E3 |