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Accessibility information
Author(s):   Awan, I.A.; Burgess, D.R.; Manion, J.A.;
Title:   Pressure Dependence and Branching Ratios in the Decomposition of 1-Pentyl Radicals: Shock Tube Experiments and Master Equation Modeling
Journal:   J. Phys. Chem. A
Volume:   116
Page(s):   2895 - 2910
Year:   2012
Reference type:   Journal article
Squib:   2012AWA/BUR2895-2910

Reaction:   n-C6H13I1-hexyl radical + I
Reaction order:   1
Temperature:   875 - 1011 K
Pressure:  1.60 - 2.10 bar
Rate expression:   4.27x1013 [±1.96x1013 s-1] e-198807 [±3608 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   GC-MS
Comments:   Uncertainties are one standard error as derived from the least squares analysis.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
875 5.79E1
900 1.24E2
925 2.54E2
950 5.01E2
975 9.54E2
1000 1.76E3
1011 2.29E3