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Author(s):   Awan, I.A.; Burgess, D.R.; Tsang, W.; Manion, J.A.;
Title:   Standard reactions for comparative rate studies: Experiments on the dehydrochlorination reactions of 2-chloropropane, chlorocyclopentane, and chlorocyclohexane
Journal:   Int J. Chem. Kinet.
Volume:   44
Page(s):   351 - 368
Year:   2012
Reference type:   Journal article
Squib:   2012AWA/BUR351-368

Reaction:   Cyclopentane, chloro-Cyclopentene + HCl
Reaction order:   1
Temperature:   843 - 1021 K
Pressure:  1.40 - 2.40 bar
Rate expression:   6.06x1013 [s-1] e-203281 [J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Shock tube
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   GC-MS
Comments:   Absolute rate constants have been derived using k(cyclohexene→ethene + butadiene) = 1.4×1015 exp(–33,500/T ) s−1.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
843 1.54E1
850 1.95E1
875 4.44E1
900 9.65E1
925 2.01E2
950 4.03E2
975 7.80E2
1000 1.46E3
1021 2.41E3