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Author(s):   Colomer, J.P.; Blanco, M.B.; Penenory, A.B.; Barnes, I.; Wiesen, P.; Teruel, M.A.
Title:   Gas-phase reactivity study of (E)-3-pentenenitrile and 4-pentenenitrile towards OH radicals and Cl atoms at atmospheric pressure
Journal:   Atmos. Environ.
Volume:   61
Page(s):   597 - 604
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012COL/BLA597-604

Reaction:   ·OH + 3-Pentenenitrile, (3E)- → Products
Reaction order:   2
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   5.05x10-11 [±1.1x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   IR absorption
Comments:   The quoted uncertainties are a combination of the 2σ statistical errors from the linear regression analysis and a contribution to cover potential errors in the reported rate coefficients of the references hydrocarbons. 1,3-Butadiene and isobutene were used as reference compounds.

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