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Author(s):   Kim, D.; Stevens, P.S.; Hites, R.A.
Title:   Kinetic isotope effects and rate constants for the gas-phase reactions of three deuterated toluenes with OH from 298 to 353 K
Journal:   Int. J. Chem. Kinet.
Volume:   44
Page(s):   821 - 827
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012KIM/STE821-827

Reaction:   C6H5CD3 + ·OH → Products
Reaction order:   2
Reference reaction:   Toluene + ·OH → Products
Temperature:   298 - 353 K
Pressure:  1.01 bar
Rate expression:   6.42x10-13 [cm3/molecule s] e5496 [±449 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The errors represent standard errors. The uncertainty in the preexponential factor is expressed as follows: A = (0.642 (+0.117 / -0.099))x10-12 cm3 molecule-1 s-1.).

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 5.90E-12
300 5.81E-12
325 4.91E-12
350 4.24E-12
353 4.18E-12