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Accessibility information
Author(s):   Kim, D.; Stevens, P.S.; Hites, R.A.
Title:   Kinetic isotope effects and rate constants for the gas-phase reactions of three deuterated toluenes with OH from 298 to 353 K
Journal:   Int. J. Chem. Kinet.
Volume:   44
Page(s):   821 - 827
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012KIM/STE821-827

Reaction:   C6D5CH3 + ·OH → Products
Reaction order:   2
Reference reaction:   Toluene + ·OH → Products
Temperature:   300 - 353 K
Pressure:  1.01 bar
Rate expression:   2.11x10-12 [cm3/molecule s] e2386 [±1064 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The errors represent standard errors. The uncertainty in the preexponential factor is expressed as follows: A = (2.11 (+1.03 / -0.69))x10-12 cm3 molecule-1 s-1.).

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 5.49E-12
325 5.10E-12
350 4.79E-12
353 4.76E-12