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Author(s):   Nilsson, E.JK.; Andersen, V.F.; Nielsen, O.J.; Johnson, M.S.
Title:   Rate coefficients for the chemical reactions of CH2F2, CHClF2, CH2FCF3 and CH3CCl3 with O(D-1) at 298 K
Journal:   Chem. Phys. Lett.
Volume:   554
Page(s):   27 - 32
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012NIL/AND27-32

Reaction:   O(1D) + CH2F2 → Products
Reaction order:   2
Reference reaction:   O(1D) + CH4 → Products
Temperature:   298 K
Pressure:  2.00E-3 - 5.00E-2 bar
Rate expression:   4.78x10-11 [±1.03x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   This is the rate constant for the overall chemical reaction, with quenching excluded. The error bars include uncertainty in the slope of the relative rate plots, uncertainty in the rate constant of the reference reaction, and an additional 5% error to take into account possible errors in the model simulations.

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