Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Parker, D.SN.; Zhang, F.; Kim, Y.S.; Kaiser, R.I.; Landera, A.; Mebel, A.M.
Title:   On the formation of phenyldiacetylene (C6H5CCCCH) and D5-phenyldiacetylene (C6D5CCCCH) studied under single collision conditions
Journal:   Phys. Chem. Chem. Phys.
Volume:   14
Page(s):   2997 - 3003
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012PAR/ZHA2997-3003

Reaction:   1,3-Butadiyne + Phenyl → Phenylbutadiyne +
Reaction order:   2
Rate expression:   no rate data available
Category:  Experiment
Data type:   Mechanistic information only
Pressure dependence:   None reported
Experimental procedure:   Molecular beam
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The crossed molecular beam reactions of the phenyl and D5-phenyl radical with diacetylene were studied under single collision conditions at a collision energy of 46 kJ/mol. No thermal rate constant values were obtained.

View full bibliographic record.