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Author(s):   Plane, J.MC.; Whalley, C.L.; Frances-Soriano, L.; Goddard, A.; Harvey, J.N.; Glowacki, D.R.; Viggiano, A.A.
Title:   O-2(a(1)Delta(g))+Mg, Fe, and Ca: Experimental kinetics and formulation of a weak collision, multiwell master equation with spin-hopping
Journal:   J. Chem. Phys.
Volume:   137
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012PLA/WHA14310

Reaction:   O2(1DELTA) + MgMgO2
Reaction order:   3
Temperature:   296 K
Pressure:  3.33E-3 - 1.33E-2 bar
Rate expression:   1.8x10-30 [±2.0x10-31 cm6/molecule2 s]
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is low pressure limit
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Thermal
Time resolution:   By end product analysis
Analytical technique:   Laser induced fluorescence
Comments:   The quoted uncertainties are the standard errors from kinetics plots. The total uncertainty, which mostly arises from the systematic uncertainty in the singlet oxygen concentration, is estimated to be ±40%.

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