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Author(s):   Renbaurn-Wolff, L.; Smith, G.D.
Title:   "Virtual Injector" Flow Tube Method for Measuring Relative Rates Kinetics of Gas-Phase and Aerosol Species
Journal:   J. Phys. Chem. A
Volume:   116
Page(s):   6664 - 6674
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012REN/SMI6664-6674

Reaction:   d-Limonene + ·Cl → Products
Reaction order:   2
Reference reaction:   CH2=C(CH3)CH=CH2 + ·Cl → Products
Temperature:   298 K
Pressure:  1.01 bar
Rate expression:   5.9x10-10 [±6.0x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The technique of "virtual injector" with laser photolysis at 10 Hz and product detection by a chemical ionization mass spectrometer was used.

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