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Author(s):   Solaka, S.A.; Boshamer, S.E.; Parworth, C.L.; Heard, G.L.; Setser, D.W.; Holmes, B.E.
Title:   Isomerisation of CF2ClCH2Cl and CFCl2CH2F by Interchange of Cl and F Atoms with Analysis of the Unimolecular Reactions of Both Molecules
Journal:   CHEMPHYSCHEM
Volume:   13
Page(s):   869 - 878
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012SOL/BOS869-878

Reaction:   ·CClF2 + ·CH2ClCF2ClCH2Cl
Reaction order:   2
Temperature:   298 K
Rate expression:   no rate data available
Category:  Experiment
Data type:   Mechanistic information only
Pressure dependence:   Rate constant is pressure dependent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Gas chromatography
Comments:   Chemically activated reactions (HCl and HF elimination, isomerization via Cl-F exchange, and collisional stabilization) were studied as functions of pressure. Exact pressure ranges are not reported. No thermal rate constants are reported. The results are interpreted in terms of the effective channel-specific (energy-dependent) rate constants at the energy of the entrance channel.

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