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Author(s):   Suarez-Bertoa, R.; Picquet-Varrault, B.; Tamas, W.; Pangui, E.; Doussin, J.F.
Title:   Atmospheric Fate of a Series of Carbonyl Nitrates: Photolysis Frequencies and OH-Oxidation Rate Constants
Journal:   Environ. Sci. Technol.
Volume:   46
Page(s):   12502 - 12509
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012SUA/PIC12502-12509

Reaction:   ·OH + CH3C(O)CH2(ONO2) → Products
Reaction order:   2
Reference reaction:   CH3OH + ·OH → Products
Temperature:   298 K
Pressure:  1.00 bar
Rate expression:   6.7x10-13 [±2.5x10-13 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   The overall uncertainties were calculated by adding the relative uncertainty corresponding to the statistical error and the error in the reference rate constant (here 20% for methanol). The statistical error was set at 2σ, (where σ is the standard deviation on the linear regression).

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