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Author(s):   Womack, C.C.; Ratliff, B.J.; Butler, L.J.; Lee, S.H.; Lin, J.JM.
Title:   Photoproduct Channels from BrCD2CD2OH at 193 nm and the HDO plus Vinyl Products from the CD2CD2OH Radical Intermediate
Journal:   J. Phys. Chem. A
Volume:   116
Page(s):   6394 - 6407
Year:   2012
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2012WOM/RAT6394-6407

Reaction:   ·CD2CD2OH → CD2O + ·CHD2
Reaction order:   1
Rate expression:   no rate data available
Category:  Experiment
Data type:   Mechanistic information only
Experimental procedure:   Molecular beam
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   Upon photolysis of BrCD2CD2OH, products of secondary dissociation of vibrationally excited CD2CD2OH radicals were detected. Relative contributions of various decomposition channels was analyzed.

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