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©NIST, 2013
Accessibility information
Author(s):   Baasandorj, M.; Fleming, E.L.; Jackman, C.H.; Burkholder, J.B.
Title:   O(D-1) Kinetic Study of Key Ozone Depleting Substances and Greenhouse Gases
Journal:   J. Phys. Chem. A
Volume:   117
Page(s):   2434 - 2445
Year:   2013
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2013BAA/FLE2434-2445

Reaction:   O(1D) + CF3CHFCF3 → Products
Reaction order:   2
Temperature:   296 K
Pressure:  0.24 bar
Rate expression:   6.99x10-12 [±5.0x10-13 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   This rate constant represents the reactive channel only, with quenching excluded. The value is the average of three determinations, where NF3, CF3CHF2, and CHF3 were used as reference compounds.

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