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Author(s):   Onel, L.; Thonger, L.; Blitz, M. A.; Seakins, P. W.; Bunkan, A. J. C.; Solimannejad, M.; Nielsen, C. J.
Title:   Gas-Phase Reactions of OH with Methyl Amines in the Presence or Absence of Molecular Oxygen. An Experimental and Theoretical Study
Journal:   J. Phys. Chem. A
Volume:   117
Page(s):   10736 - 10745
Year:   2013
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2013ONE/THO10736-10745

Reaction:   CH3NH2 + ·OH → Products
Reaction order:   2
Temperature:   298 - 600 K
Pressure:  6.67E-3 - 3.33E-2 bar
Rate expression:   1.89x10-11 [±5.3x10-13 cm3/molecule s] (T/298 K)(-0.56±0.10)
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Uncertainties are 2σ.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 1.89E-11
300 1.88E-11
325 1.80E-11
350 1.73E-11
375 1.66E-11
400 1.60E-11
425 1.55E-11
450 1.50E-11
475 1.45E-11
500 1.41E-11
525 1.38E-11
550 1.34E-11
575 1.31E-11
600 1.28E-11