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Author(s):   Onel, L.; Thonger, L.; Blitz, M. A.; Seakins, P. W.; Bunkan, A. J. C.; Solimannejad, M.; Nielsen, C. J.
Title:   Gas-Phase Reactions of OH with Methyl Amines in the Presence or Absence of Molecular Oxygen. An Experimental and Theoretical Study
Journal:   J. Phys. Chem. A
Volume:   117
Page(s):   10736 - 10745
Year:   2013
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2013ONE/THO10736-10745

Reaction:   CH3NH2 + ·OH → Other Products + H2O
Reaction order:   2
Temperature:   200 - 600 K
Rate expression:   no rate data available
Category:  Theory
Data type:   Transition state theory
Pressure dependence:   Rate constant is pressure independent
Comments:   Reaction potential energy surface was studied using quantum chemistry and rate constants were calculated using transition state theory. Rate constants were calculated for a wide range of temperatures; however, no Arrhenius expression is given for the k(T) dependence. Instead, rate constants and channel-specific abstraction branching fractions for individual temperatures are presented in a tabular format in the supporting information.

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