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Accessibility information
Author(s):   Chai, J. J.; Hu, H. Y.; Dibble, T. S.; Tyndall, G. S.; Orlando, J. J.
Title:   Rate Constants and Kinetic Isotope Effects for Methoxy Radical Reacting with NO2 and O2
Journal:   J. Phys. Chem. A
Volume:   118
Page(s):   3552 - 3563
Year:   2014
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2014CHA/HU,3552-3563

Associated entries:

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Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2014CHA/HU,3552-3563   CH3 + NO2 → Products  250 - 333   4.86E-12       -3110   1.70E-11  2
  2014CHA/HU,3552-3563   CD3O + NO2 → Products  250 - 335   5.59E-12       -2893   1.80E-11  2
  2014CHA/HU,3552-3563   CD3O + O2CD2O + DO2  250 - 335   8.20E-15       8098   3.12E-16  2
  2014CHA/HU,3552-3563   CH3 + O2CH2O + HO2  250 - 335   1.30E-14       5512   1.41E-15  2
  2014CHA/HU,3552-3563   CH3 + O2CH2O + HO2  250 - 335   1.70       -2544   4.75  2
  Reference reaction:  CD3O + O2CD2O + DO2 2
  2014CHA/HU,3552-3563   CH3 + O2CH2O + HO2  250 - 610   3.30E-15   2.40   1729   1.64E-15  2

Search returned 6 records.