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©NIST, 2013
Accessibility information
Author(s):   Chai, J. J.; Hu, H. Y.; Dibble, T. S.; Tyndall, G. S.; Orlando, J. J.
Title:   Rate Constants and Kinetic Isotope Effects for Methoxy Radical Reacting with NO2 and O2
Journal:   J. Phys. Chem. A
Volume:   118
Page(s):   3552 - 3563
Year:   2014
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2014CHA/HU,3552-3563

Reaction:   CH3 + NO2 → Products
Reaction order:   2
Temperature:   250 - 333 K
Pressure:  0.93 bar
Rate expression:   4.86x10-12 [±4.0x10-13 cm3/molecule s] e3110 [±200 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Error bars are 1σ of the precision of the fit.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
250 2.17E-11
275 1.89E-11
300 1.69E-11
325 1.54E-11
333 1.49E-11