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©NIST, 2013
Accessibility information
Author(s):   Cho, J.; Roueintan, M.; Li, Z. J.
Title:   Kinetic and Dynamic Investigations of OH Reaction with Styrene
Journal:   J. Phys. Chem. A
Volume:   118
Page(s):   9460 - 9470
Year:   2014
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2014CHO/ROU9460-9470

Reaction:   Styrene + ·OH → Products
Reaction order:   2
Temperature:   298 - 340 K
Pressure:  1.33E-3 - 4.00E-3 bar
Rate expression:   1.02x10-11 [±1.0x10-12 cm3/molecule s] e4423 [±233 J/mole]/RT
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   Isoprene, 1,3-butadiene, naphthalene, and propanal were used as reference compounds.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
298 6.08E-11
300 6.01E-11
325 5.24E-11
340 4.88E-11