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Accessibility information
Author(s):   Matsugi, A.; Shiina, H.
Title:   Kinetics of Hydrogen Abstraction Reactions from Fluoromethanes and Fluoroethanes
Journal:   Bull. Chem. Soc. Jpn.
Volume:   87
Page(s):   890 - 901
Year:   2014
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2014MAT/SHI890-901

Reaction:   CH2F2 + H2 + ·CHF2
Reaction order:   2
Temperature:   300 - 2500 K
Rate expression:   5.22x10-13 [cm3/molecule s] (T/298 K)2.83 e-30930 [J/mole]/RT
Category:  Theory
Data type:   Ab initio

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 2.19E-18
400 1.10E-16
500 1.33E-15
600 7.68E-15
700 2.88E-14
800 8.17E-14
900 1.91E-13
1000 3.89E-13
1100 7.15E-13
1200 1.21E-12
1300 1.93E-12
1400 2.92E-12
1500 4.24E-12
1600 5.94E-12
1700 8.09E-12
1800 1.07E-11
1900 1.39E-11
2000 1.78E-11
2100 2.23E-11
2200 2.76E-11
2300 3.37E-11
2400 4.06E-11
2500 4.85E-11