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Accessibility information
Author(s):   Sharath, N.; Reddy, K. P. J.; Arunan, E.
Title:   Thermal Decomposition of Propargyl Alcohol: Single Pulse Shock Tube Experimental and ab Initio Theoretical Study
Journal:   J. Phys. Chem. A
Volume:   118
Page(s):   5927 - 5938
Year:   2014
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2014SHA/RED5927-5938

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2014SHA/RED5927-5938   CH2C≡CH + CH2C≡CHBenzene  953 - 1262   1.47E-10   0.10   5.02E04      2
  2014SHA/RED5927-5938   HC≡CCH2OHCH2O + C2H2  953 - 1262   3.39E13       3.71E05      1
  2014SHA/RED5927-5938   HC≡CCHOC2H2 + CO  953 - 1262   4.57E14       3.61E05      1
  2014SHA/RED5927-5938   HCCCH2O· → ·HC=CHCHO  953 - 1262   3.31E13       1.01E05      1
  2014SHA/RED5927-5938   HCCCH2O· → HC≡CCHO +   953 - 1262   4.37E13       1.39E05      1
  2014SHA/RED5927-5938   CH2=C=CHOH → CH2=CHCHO  953 - 1262   1.55E13       2.36E05      1
  2014SHA/RED5927-5938   ·CH2CH=CO → CO + C2H3  953 - 1262   2.09E14       1.45E05      1
  2014SHA/RED5927-5938   ·HC=CHCHO → C2H2 + HCO  953 - 1262   1.70E14       1.72E05      1
  2014SHA/RED5927-5938   HC≡CCH2OH + ·OH → HCCCH2O· + H2O  953 - 1262   4.27E-12       1.03E05      2
  2014SHA/RED5927-5938   HC≡CCH2OH + → HCCCH2O· + ·OH  953 - 1262   1.07E-10       1.05E05      2
  2014SHA/RED5927-5938   CH2=CHCHO + → ·CH2CH=CO + H2  953 - 1262   1.95E-10       6.90E04      2
  2014SHA/RED5927-5938   HC≡CCH2OH + ·OH → HCCCH2O· + H2O  953 - 1262   6.90E-10   0.25   1.03E05      2
  2014SHA/RED5927-5938   HC≡CCH2OH + → HCCCH2O· + H2  953 - 1262   6.33E-09   0.25   1.05E05      2
  2014SHA/RED5927-5938   CH2=CHCHO + → ·CH2CH=CO + H2  953 - 1262   7.34E-09   0.30   6.90E04      2
  2014SHA/RED5927-5938   CH2=CHCHO + ·OH → ·CH2CH=CO + H2O  953 - 1262   1.66E-09       6.90E04      2
  2014SHA/RED5927-5938   HC≡CCH2OHCH2=CHCHO  953 - 1262   1.00E15       2.11E05      1
  2014SHA/RED5927-5938   HCCCH2O· → ·HC=CHCHO  953 - 1262   5.00E13       9.46E04      1
  2014SHA/RED5927-5938   HCCCH2O· → HC≡CCHO +   953 - 1262   6.00E16       1.39E05      1
  2014SHA/RED5927-5938   ·HC=CHCHO → C2H2 + HCO  953 - 1262   1.71E14       1.72E05      1
  2014SHA/RED5927-5938   ·CH2CH=CO → CO + C2H3  953 - 1262   2.10E14       1.45E05      1

Search returned 20 records.