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Author(s):   Bunkan, A. J. C.; Hetzler, J.; Mikoviny, T.; Wisthaler, A.; Nielsen, C. J.; Olzmann, M.
Title:   The reactions of N-methylformamide and N,N-dimethylformamide with OH and their photo-oxidation under atmospheric conditions: experimental and theoretical studies
Journal:   Phys. Chem. Chem. Phys.
Volume:   17
Page(s):   7046 - 7059
Year:   2015
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2015BUN/HET7046-7059

Reaction:   HCONHCH3 + ·OH → Products
Reaction order:   2
Temperature:   260 - 295 K
Pressure:  3.00E-2 - 0.60 bar
Rate expression:   1.3x10-12 [±4.0x10-13 cm3/molecule s] e3700 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure dependent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   The rate coefficient shows very weak positive pressure dependence. The Arrhenius equation given, within its uncertainty, is valid for the entire pressure range of experiments.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
260 7.20E-12
275 6.56E-12
295 5.88E-12