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Author(s):   Bunkan, A. J. C.; Hetzler, J.; Mikoviny, T.; Wisthaler, A.; Nielsen, C. J.; Olzmann, M.
Title:   The reactions of N-methylformamide and N,N-dimethylformamide with OH and their photo-oxidation under atmospheric conditions: experimental and theoretical studies
Journal:   Phys. Chem. Chem. Phys.
Volume:   17
Page(s):   7046 - 7059
Year:   2015
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2015BUN/HET7046-7059

Reaction:   HCONHCH3 + ·OH → Products
Reaction order:   2
Temperature:   260 - 295 K
Rate expression:   no rate data available
Category:  Theory
Data type:   Transition state theory
Pressure dependence:   Rate constant is high pressure limit
Comments:   Reaction potential energy surface was studied using quantum chemistry and rate constants were calculated using transition state theory. Model properties were adjusted to fit experimental data. No Arrhenius expression is provided. Instead, the k(T) dependence is presented in a graphical format.

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