Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2020
Accessibility information
Author(s):   Nicovich, J. M.; Mazumder, S.; Laine, P. L.; Wine, P. H.; Tang, Y.; Bunkan, A. J. C.; Nielsen, C. J.
Title:   An experimental and theoretical study of the gas phase kinetics of atomic chlorine reactions with CH3NH2, (CH3)2NH, and (CH3)3N
Journal:   Phys. Chem. Chem. Phys.
Volume:   17
Page(s):   911 - 917
Year:   2015
Book Title:   ''
Editor:   ''
Publisher:   ''
Publisher address:   ''
Comments:   ''
Reference type:   Journal article
Squib:   2015NIC/MAZ911-917

Reaction:   CH3NH2 + ·Cl → Products
Reaction order:   2
Temperature:   296 - 419 K
Pressure:  3.33E-2 - 0.27 bar
Rate expression:   2.63x10-10 [±3.0x10-11 cm3/molecule s] e274 [±316 J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   Rate constant is pressure independent
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Flash photolysis (laser or conventional)
Time resolution:   In real time
Analytical technique:   Laser induced fluorescence
Comments:   Uncertainties in the Arrhenius expression are 2σ and represent the precision of the Arrhenius parameters.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
296 2.94E-10
300 2.94E-10
325 2.91E-10
350 2.89E-10
375 2.87E-10
400 2.86E-10
419 2.85E-10