Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences


Rate Our Products and Services


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty


Administrative Links

NIST home page

MML home page

Chemical Sciences Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Cobos, C.J.; Knight, G.; Soelter, L.; Tellbach, E.; Troe, J.
Title:   Shock Wave and Theoretical Modeling Study of the Dissociation of CH2F2. II. Secondary Reactions
Journal:   J. Phys. Chem. A
Volume:   121
Page(s):   7820 - 7826
Year:   2017
Reference type:   Journal article
Squib:   2017COB/KNI7820-7826

Reaction:   CH2F2 + ·CHF·CHF2 + ·CH2F
Reaction order:   2
Temperature:   1000 - 2500 K
Rate expression:   7.92x10-16 [cm3/molecule s] (T/298 K)3.20 e-44399 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory
Pressure dependence:   Rate constant is pressure independent
Comments:   Reaction potential energy surface was studied using quantum chemistry and rate constants were calculated using statistical rate theories.

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
1000 1.83E-16
1100 4.03E-16
1200 7.98E-16
1300 1.45E-15
1400 2.47E-15
1500 3.97E-15
1600 6.09E-15
1700 9.00E-15
1800 1.29E-14
1900 1.79E-14
2000 2.43E-14
2100 3.22E-14
2200 4.19E-14
2300 5.37E-14
2400 6.78E-14
2500 8.45E-14