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Author(s):   Andersen, S.T.; Hass, S.A.; Frederickson, L.B.; Nielsen, O.J.
Title:   Atmospheric Chemistry of n-CH2 = CH(CH2)(x)CN (x=0-4): Kinetics and Mechanisms
Journal:   J. Phys. Chem. A
Volume:   122
Page(s):   5983 - 5992
Year:   2018
Reference type:   Journal article
Squib:   2018AND/HAS5983-5992

Reaction:   CH2CHCN + ·Cl → Products
Reaction order:   2
Temperature:   296 K
Pressure:  0.93 bar
Rate expression:   1.03x10-10 [±1.3x10-11 cm3/molecule s]
Category:  Experiment
Data type:   Relative value normalized by a reference value
Pressure dependence:   None reported
Experimental procedure:   Static or low flow - Data taken vs time
Excitation technique:   Direct photolysis
Time resolution:   By end product analysis
Analytical technique:   Fourier transform (FTIR)
Comments:   Ethylene and propylene were used as treference compounds. The uncertainties encompass the extremes of the individual determinations.

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