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©NIST, 2013
Accessibility information
Author(s):   Bedjanian, Y.
Title:   Kinetics and Products of the Reaction of OH Radicals with CINO from 220 to 940 K
Journal:   J. Phys. Chem. A
Volume:   122
Page(s):   916 - 922
Year:   2018
Reference type:   Journal article
Squib:   2018BED916-922

Reaction:   NOCl + ·OHHOCl + NO
Reaction order:   2
Temperature:   220 - 940 K
Pressure:  2.67E-3 bar
Rate expression:   3.05x10-13 [cm3/molecule s] (T/298 K)1.99 e-948 [J/mole]/RT
Uncertainty:   1.20000005
Category:  Experiment
Data type:   Absolute value measured directly
Pressure dependence:   None reported
Experimental procedure:   Flow tube - Data taken vs distance
Excitation technique:   Discharge
Time resolution:   By end product analysis
Analytical technique:   Mass spectrometry
Comments:   The uncertainty is estimated at 20%.

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
220 9.94E-14
250 1.36E-13
300 2.12E-13
350 3.04E-13
400 4.13E-13
450 5.38E-13
500 6.81E-13
550 8.40E-13
600 1.02E-12
650 1.21E-12
700 1.42E-12
750 1.65E-12
800 1.89E-12
850 2.15E-12
900 2.43E-12
940 2.66E-12