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Accessibility information
Author(s):   Guerra, N.C.L.; Huerta, J.C.L.; Lorgeoux, C.; Michels, R.; Fournet, R.; Sirjean, B.; Randi, A.; Bounaceur, R.; Burkle-Vitzthum, V.
Title:   Thermal cracking of n-butylbenzene at high pressure: Experimental study and kinetic modelling
Journal:   J. Anal. Appl.Pyrolsis
Volume:   133
Page(s):   234 - 245
Year:   2018
Reference type:   Journal article
Squib:   2018GUE/HUE234-245

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  2018GUE/HUE234-245   1-butylbenzene + PhenylBenzene + 1-phenylbutyl  473 - 673   3.48E-14   3.62   -3598      2
  2018GUE/HUE234-245   1-butylbenzene + Phenyl → C6H5CH2CH2CH(·)CH3 + Benzene  473 - 673   4.59E-14   3.95   3347      2
  2018GUE/HUE234-245   1-butylbenzene + Phenyl → C6H5CH2CH2CH2CH2· + Benzene  473 - 673   4.41E-15   4.19   1.83E04      2
  2018GUE/HUE234-245   1-butylbenzene + BenzylToluene + 1-phenylbutyl  473 - 673   1.67E-15   3.93   4.08E04      2
  2018GUE/HUE234-245   1-butylbenzene + Benzyl → C6H5CH2CH2CH(·)CH3 + Toluene  473 - 673   8.75E-15   3.98   6.30E04      2
  2018GUE/HUE234-245   1-butylbenzene + Benzyl → C6H5CH2CH2CH2CH2· + Toluene  473 - 673   3.71E-15   3.96   7.76E04      2
  2018GUE/HUE234-245   1-butylbenzene + 1-phenylethylEthylbenzene + 1-phenylbutyl  473 - 673   5.32E-16   4.23   4.28E04      2
  2018GUE/HUE234-245   1-butylbenzene + 1-phenylethyl → C6H5CH2CH2CH(·)CH3 + Ethylbenzene  473 - 673   3.90E-15   4.21   6.82E04      2
  2018GUE/HUE234-245   1-butylbenzene + 1-phenylethyl → C6H5CH2CH2CH2CH2· + Ethylbenzene  473 - 673   4.93E-15   4.15   8.40E04      2
  2018GUE/HUE234-245   1-butylbenzene + 2-phenylethyl → Ethylbenzene + 1-phenylbutyl  473 - 673   1.35E-15   4.30   1.74E04      2
  2018GUE/HUE234-245   1-butylbenzene + 2-phenylethyl → C6H5CH2CH2CH(·)CH3 + Ethylbenzene  473 - 673   1.92E-15   4.56   3.15E04      2
  2018GUE/HUE234-245   1-butylbenzene + 2-phenylethyl → C6H5CH2CH2CH2CH2· + Ethylbenzene  473 - 673   5.84E-16   4.62   4.13E04      2
  2018GUE/HUE234-245   Ethylbenzene + ·CH3Toluene + 1-C4H9  473 - 673   1.46E-15   2.54   4.74E04      2
  2018GUE/HUE234-245   Ethylbenzene + ·CH2CH=CH23-Phenylpropene + 1-C4H9  473 - 673   4.67E-14   2.19   1.06E05      2
  2018GUE/HUE234-245   1-phenylbutyl → C6H5CH2CH2CH(·)CH3  473 - 673   9.36E09   2.83   1.70E05      1
  2018GUE/HUE234-245   C6H5CH2CH(·)CH2CH3 → C6H5CH2CH2CH2CH2·  473 - 673   6.25E09   3.53   1.42E05      1
  2018GUE/HUE234-245   1-phenylbutyl → C6H5CH2CH2CH2CH2·  473 - 673   7.42E09   2.17   1.16E05      1
  2018GUE/HUE234-245   1-phenylbutyl → Styrene + ·C2H5  473 - 673   5.32E14   0.26   1.52E05      1
  2018GUE/HUE234-245   C6H5CH2CH(·)CH2CH31-C4H8 + Phenyl  473 - 673   7.83E13   0.72   1.65E05      1
  2018GUE/HUE234-245   C6H5CH2CH(·)CH2CH33-Phenylpropene + ·CH3  473 - 673   2.49E13   0.81   1.24E05      1
  2018GUE/HUE234-245   C6H5CH2CH2CH(·)CH3CH3CH=CH2 + Benzyl  473 - 673   3.56E12   0.99   8.99E04      1
  2018GUE/HUE234-245   C6H5CH2CH2CH2CH2· → C2H4 + 2-phenylethyl  473 - 673   2.23E13   0.38   1.21E05      1
  2018GUE/HUE234-245   C6H5CH2CH2CH2CH2· → 1,2,3,4,10-pentahydronapthalen-5-yl  473 - 673   4.63E08   1.11   4.13E04      1
  2018GUE/HUE234-245   1,2,3,4,10-pentahydronapthalen-5-yl → 1,2,3,4-Tetrahydronaphthalene +   473 - 673   1.13E13   0.83   1.21E05      1
  2018GUE/HUE234-245   1-butylbenzeneCH3CH=CH2 + 5-Methylene 1,3-cyclohexadiene  473 - 673   8.44E10   1.82   2.85E05      1

Search returned 25 records.