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Author(s):   Sleiman, C.; El Dib, G.; Rosi, M.; Skouteris, D.; Balucani, N.; Canosa, A.
Title:   Low temperature kinetics and theoretical studies of the reaction CN + CH3NH2: a potential source of cyanamide and methyl cyanamide in the interstellar medium
Journal:   Phys. Chem. Chem. Phys.
Volume:   20
Page(s):   5478 - 5489
Year:   2018
Reference type:   Journal article
Squib:   2018SLE/ELD5478-5489

Reaction:   CN + CH3NH2H2NCN + ·CH3
Reaction order:   2
Temperature:   36.00 - 297 K
Rate expression:   3.72x10-12 [cm3/molecule s] (T/298 K)-1.80 e-64.77 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory
Pressure dependence:   Rate constant is low pressure limit
Comments:   Electronic structure calculations of the underlying potential energy surface have been performed, together with capture theory and RRKM calculations.

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Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
36.00 1.35E-10
50.00 7.92E-11
75.00 4.02E-11
100 2.46E-11
125 1.67E-11
150 1.22E-11
175 9.29E-12
200 7.34E-12
225 5.97E-12
250 4.95E-12
275 4.18E-12
297 3.65E-12