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CH2Cl2 + ·Cl → CHCl2 + HCl

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
Review
  2001ATK/BAU1-56   270 - 370   2.80E-11       1.08E04   3.57E-13  2
  1999ORL515-524   222 - 298   1.50E-11       9146      2
  1997DEM/SAN1-266   200 - 300   3.11E-11       1.12E04   3.35E-13  2
  1997ATK/BAU521-1011   270 - 370   2.81E-11       1.08E04   3.58E-13  2
  1994DEM/SAN   200 - 300   3.11E-11       1.12E04   3.35E-13  2
  1992ATK/BAU1125-1568   270 - 330   8.70E-12       7566   4.11E-13  2
 
Experiment
  2011SAR/GOL220-225   298 - 527   8.69E-12       7940   3.53E-13  2
  2002BRY/SLA10532-10542   296 - 790   1.20E-12   1.58   2993   3.59E-13  2
  1996CAT/LES14356-14371   298   3.50E-13           3.50E-13  2
  1988TSC/FAR1488-1495   273 - 298   4.63E-11       1.23E04      2
  1980NIK/MAK1001   298   3.80E-13           3.80E-13  2
  1973CLY/WAL1547-1567   298 - 621   8.37E-11       1.21E04   6.45E-13  2
  1970DAV/BRA101-114   298   5.50E-13           5.50E-13  2
  1962KNO275-283   283 - 563   4.48E-11       1.26E04   2.82E-13  2
  1961GOL/HUY2210-2219   357 - 477   4.17E-11       1.31E04      2
  1958GOL/JEU456-458   358 - 563   6.61E-10       2.30E04      2
  2012KAI/WAL5958-5971   470   1.94              2
  Reference reaction:  CH4 + ·Cl → ·CH3 + HCl 2
  1996CAT/LES14356-14371   298   3.51           3.51  2
  Reference reaction:  CH4 + ·Cl → ·CH3 + HCl 2
  1995BEI/WIN13156-13162   298   3.45           3.45  2
  Reference reaction:  CH4 + ·Cl → ·CH3 + HCl 2
  1988TSC/FAR1488-1495   273 - 298   2.81       -407      2
  Reference reaction:  CH4 + ·Cl → ·CH3 + HCl 2
  1962KNO275-283   283 - 563   0.38       8481   0.01  2
  Reference reaction:  C3H8 + ·Cl → 1-C3H7 + HCl 2
  1962KNO275-283   283 - 563   0.38       9562   8.01E-03  2
  Reference reaction:  C3H8 + ·Cl → 2-C3H7 + HCl 2
 
Theory
    2012CHA/RAD3745-3752   298               0.00E00  2
    2004LI/XU20-24                      2
  2002XIA/LI320-325   200 - 700   5.96E-12   2.56   6785   3.85E-13  2
  1992SEN/QUA10837-10842   300 - 400   2.87E-11       1.07E04      2
    2003KNY11082-11091                       
Search returned 27 records.