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(CH3)3CO· → Acetone + ·CH3

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
Review
  2006CUR250-275   298 - 2000   7.80E15   -2.55   7.05E04   3485  1
  1988HEI177   298 - 450   1.00E15       6.90E04   801  1
 
Experiment
  2000FIT/HIP1677-1683   323 - 383   1.50E-08       3.85E04      2
  1967YEE/THY2970-2974   398 - 436   8.32E-09       5.60E04      2
  1967QUE/THY2970   398 - 436   8.32E-09       5.60E04      2
  2000MER/RAY3765-3772   298   4000           4000  1
  2000MER/RAY3765-3772   298   3000           3000  1
  2000FIT/HIP1677-1683   323 - 383   1.00E14       6.05E04      1
  1990PAR/SON343-347   413   1.20E06              1
  1989BAT/HIS535-546   303 - 393   1.10E14       6.25E04      1
  1987BAT/ROB391   402 - 443   3.98E14       6.69E04      1
  1982BAT/ROB172   402 - 443   7.94E14       6.94E04      1
  1982BAT/ROB172   402 - 443   3.98E14       6.65E04      1
  1982BAT/ROB1053   403 - 443   3.98E14       6.65E04      1
  1982BAT/ROB1053   403 - 1500   7.94E14       6.94E04      1
  1979BAT977   393 - 433   3.16E15       7.12E04      1
  1976BAT/MIL59   393 - 433   5.01E15       7.12E04      1
  1975BAT/MCC441   393 - 473   3.98E15       7.15E04      1
  1971CAD/TRO2296   373 - 423   2.34E13       7.02E04      1
  1967YEE/THY2970-2974   398 - 436   5.01E14       9.56E04      1
  1967QUE/THY2970   398 - 436   5.01E14       9.56E04      1
  1996KOR/SER253-273   389 - 451   7.59E25       4.90E04      1
  Reference reaction:  (CH3)2C=C(CH3)2 + (CH3)3CO· → tert-C4H9OH + CH2C(CH3)=C(CH3)2 2
  1981KIR/PAR293   298 - 333   1.20E27       7.06E04   5.08E14  1
  Reference reaction:  tert-C4H9OOH + (CH3)3CO· → tert-C4H9OH + (CH3)3CO2 2
 
Theory
  1970BRO/NEC2029   283 - 343   4.17E-09       6.53E04   1.51E-20  2
  2019TIA/LI83-92   600 - 2000   4.15E13   0.35   6.35E04      1
  2017SEB/HAB2260-2273   300 - 2400   5.10E12   1.10   5.40E04      1
  2005BUB/KLI1205-1222   200 - 700   1.30E14       6.26E04   1385  1
  2003RAU/BOY431-442       1.15E14       5.69E04      1
  1981CHO/BEN833   298 - 450   1.26E14       6.40E04   756  1
  1977BAL/BAR2483   298 - 450   1.58E15       6.65E04   3465  1
  1962THO/CAL4207   298   51.10           51.10  1
  1960MCM2422   297 - 324   1.00E11       4.61E04   844  1
  1957BIR/DAN154-164   403 - 443   5.01E09       5.52E04      1
Search returned 33 records.