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·CF3 + O2CF3O2

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
Review
  1997DEM/SAN1-266   200 - 300   3.01E-29   -4.00       3.01E-29  3
  1997ATK/BAU521-1011   200 - 300   1.90E-29   -4.70       1.90E-29  3
  1994DEM/SAN   200 - 300   3.01E-29   -4.00       3.01E-29  3
  1992ATK/BAU1125-1568   200 - 300   1.90E-29   -4.70       1.90E-29  3
  1989ATK/BAU881-1097   200 - 400   1.90E-29   -4.70       1.90E-29  3
  1997DEM/SAN1-266   200 - 300   4.00E-12   -1.00       4.00E-12  2
  1997ATK/BAU521-1011   200 - 400   1.00E-11           1.00E-11  2
  1994DEM/SAN   200 - 300   4.00E-12   -1.00       4.00E-12  2
  1992ATK/BAU1125-1568   200 - 400   1.00E-11           1.00E-11  2
  1989ATK/BAU881-1097   200 - 400   1.00E-11           1.00E-11  2
  1986TEI/VED1119   298   8.00E-12           8.00E-12  2
 
Experiment
  1995KAI/WAL205-218   296   4.80E-29              3
  1991FOR/CAR2307-2315   233 - 373   1.55E-29   -4.78       1.55E-29  3
  1988ORL/SMI5147   298   2.10E-29           2.10E-29  3
  1986TEI/VED1119   296   2.10E-29              3
  1986CAR/LES433   232 - 373   1.90E-29   -4.70       1.90E-29  3
  1985VEL/GOR58   480   6.59E-31              3
  1982RYA/PLU4678   295   1.80E-29              3
  1995KAI/WAL205-218   296   3.95E-12              2
  1991FOR/CAR2307-2315   233 - 373   6.34E-12   -0.27       6.34E-12  2
  1986CAR/LES433   233 - 373   9.00E-12           9.00E-12  2
  1982RYA/PLU4678   295   8.00E-12              2
  1980COO/CUM169   300   1.00E-11              2
  1979VED/TEI2475   253 - 343   4.90E-12       2844   1.55E-12  2
  1978VED/TEI1534-1537   296   1.50E-12              2
  1977ARU/GOR161-167   269 - 356   2.51E-11       8813   7.15E-13  2
  1979VED/TEI2475   253 - 343   1.12       -2420   2.97  2
  Reference reaction:  ·CF3 + Br2CF3Br + Br· 2
  1978VED/TEI1534-1537   296   2.90              2
  Reference reaction:  ·CF3 + Br2CF3Br + Br· 2
  1977VED/TEI480-482   256 - 345   0.82       -1.06E04   58.17  2
  Reference reaction:  ·CF3 + F2CF4 + ·F 2
  1977ARU/GOR161-167   296 - 356   3.60       -6693   53.64  2
  Reference reaction:  ·CF3 + Cl2CF3Cl + ·Cl 2
 
Theory
  1986PLU/RYA247   295   3.50E-29              3
  1986PLU/RYA205   295   3.50E-29              3
    2018SAH/JAV154-158   200 - 1600               0.00E00  2
  1986PLU/RYA205   295   8.00E-12              2
  1985COB/TRO1010-1015   300 - 1500   2.59E-11       2611      2

Search returned 35 records.