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CH3O2· + NOCH3 + NO2

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
Review
    2001WES1656-1661                      3
  2001ATK/BAU1-56   200 - 430   2.80E-12       -2370   7.29E-12  2
  1997DEM/SAN1-266   200 - 300   3.01E-12       -2328   7.69E-12  2
  1997ATK/BAU521-1011   240 - 360   4.20E-12       -1497   7.69E-12  2
  1994DEM/SAN   200 - 300   4.20E-12       -1497   7.69E-12  2
  1992WAL/DAG667-710   240 - 370   3.90E-12       -1663   7.63E-12  2
  1992ATK/BAU1125-1568   240 - 3560   4.20E-12       -1497   7.69E-12  2
  1989ATK/BAU881-1097   240 - 360   4.20E-12       -1497   7.69E-12  2
 
Experiment
  2004BAC/BAR10681-10687   193 - 300   1.75E-12       -3617   7.53E-12  2
  1996HEL/MOO17846-17854   298   7.51E-12           7.51E-12  2
  1995VIL/HUE12829-12834   199 - 429   2.81E-12       -2370   7.30E-12  2
  1994MAS/TSU523-528   298   1.12E-11           1.12E-11  2
  1993KEN/RYA1571-1574   293   9.10E-12              2
  1986ZEL/FRI241   298   7.01E-12           7.01E-12  2
  1981SIM/HEI2946   218 - 365   2.09E-12       -3159   7.49E-12  2
  1981PLU/RYA3136   295   8.60E-12              2
  1980SAN/WAT1664   298   7.11E-12           7.11E-12  2
  1980COX/TYN153   298   6.51E-12           6.51E-12  2
  1979SIM/HEI361   296   3.16E-12              2
  1979COX/TYN357   298   6.51E-12           6.51E-12  2
  1979SIM/HEI361   296   417              2
  Reference reaction:  CH3O2· + SO2 → Products 2
  1974SIM/HEI2417   298   2.20           2.20  2
  Reference reaction:  CH3O2· + NO2 → Products 2
 
Theory
  1976COX/DER2044   298   >1.20E-12           1.20E-12  2

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