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CH3 + O2CH2O + HO2

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
Review
    2001WES1656-1661                      3
  2003ORL/TYN4657-4689   298 - 610   7.82E-14       9562   1.65E-15  2
  2001ATK/BAU1-56   298 - 610   7.20E-14       8980   1.92E-15  2
  1997DEM/SAN1-266   200 - 300   3.90E-14       7483   1.90E-15  2
  1997ATK/BAU521-1011   298 - 610   7.21E-14       8980   1.92E-15  2
  1997ATK99-111   298 - 600   7.21E-14       8980   1.92E-15  2
  1994DEM/SAN   200 - 300   3.90E-14       7483   1.90E-15  2
  1994BAU/COB847-1033   300 - 1000   3.60E-14       7317      2
  1992BAU/COB411-429   300 - 1000   5.99E-14       8896      2
  1992ATK/BAU1125-1568   298 - 610   7.21E-14       8980   1.92E-15  2
  1989ATK/BAU881-1097   298 - 610   7.21E-14       8980   1.92E-15  2
  1988HEI177   298 - 628   8.52E-14       1.07E04   1.12E-15  2
  1986TSA/HAM1087   300 - 2500   1.10E-13       1.09E04      2
  1984WAR197C   300 - 2000   1.66E-11       3.00E04      2
 
Experiment
  1989BAL/POR483-488   384 - 425   3.90E-13       1.50E04      2
  1988ZAS/MUK244   700 - 900   1.05E-13       1.09E04      2
  1987ZEL403-407   298 - 425   5.50E-14       8314   1.92E-15  2
  1987WAN/OLD4653   298 - 973   2.32E-19   9.50   -2.30E04   2.53E-15  2
  1985LOR/RHA341   298 - 450   5.50E-14       8314   1.92E-15  2
  1982GUT/SAN66   413 - 628   1.05E-13       1.09E04      2
  1981KIR/PAR293   373   >7.01E-15              2
  1980SAN/BUT17   298   <1.66E-15           1.66E-15  2
  1980COX/DER149   296 - 450   1.26E-13       1.12E04   1.36E-15  2
  1979BAT/ROB1045   383 - 433   1.66E-12       2.01E04      2
  1979BAT/RAT1183   383 - 433   1.66E-12       1.88E04      2
  1977BAR/BEN31   396 - 442   5.25E-13       1.67E04      2
  1975ALC/MIL125   373   1.99E-15              2
  1989BAL/POR483-488   384 - 425   0.58       -4989      2
  Reference reaction:  iso-C4H10 + CH3CH3OH + tert-C4H9 2
  1981KIR/PAR293   373   <0.40              2
  Reference reaction:  tert-C4H9OOH + CH3CH3OH + (CH3)3CO2 2
  1981KIR/PAR293   373   <0.40              2
  Reference reaction:  tert-C4H9OOH + CH3 → Products 2
  1977ALC/MIL133   373   5.79              2
  Reference reaction:  (CH3)2CHCH(CH3)2 + CH3CH3OH + (CH3)2CHC(·)(CH3)2 2
  1977ALC/MIL133   373   3.30              2
  Reference reaction:  (CH3)2CHCH(CH3)2 + CH3O2·CH3OOH + (CH3)2CHC(·)(CH3)2 2
  1975GLA1048   296   <7.40E-05              2
  Reference reaction:  CH3 + NO2CH3ONO2 2
  1975GLA1048   296   5.20E-05              2
  Reference reaction:  CH3 + NOCH3ONO 2
  1973WIE/VIL7   298   4.70E-05           4.70E-05  2
  Reference reaction:  CH3 + NO → Products 2
  1968HOA/LI136   603   20.00              2
  Reference reaction:  (CH3)2CO + CH3CH3OH + CH3C(O)CH2(·) 2
 
Theory
    2007MAR/ROS11652-11660                      2
    2006ROS/FRA4419-4433                      2
  1980MOS/POL315   593 - 626   1.76E-03       1.36E05      2
  1977ALC/MIL133   373   1.99E-15              2
  1975MEN/GOL725   300   5.81E-16              2

Search returned 41 records.