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·OH + H2O2HO2 + H2O

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
Review
  2004ATK/BAU1461-1738   298   1.70E-12           1.70E-12  2
  2004ATK/BAU1461-1738   240 - 460   2.90E-12       1330   1.70E-12  2
  2001ATK/BAU1-56   240 - 460   2.90E-12       1330   1.70E-12  2
  1997DEM/SAN1-266   200 - 300   2.91E-12       1330   1.70E-12  2
  1997ATK/BAU1329-1499   240 - 460   2.91E-12       1330   1.70E-12  2
  1994DEM/SAN   200 - 300   2.91E-12       1330   1.70E-12  2
  1992BAU/COB411-429   300 - 1000   1.30E-11       5571      2
  1992ATK/BAU1125-1568   240 - 460   2.91E-12       1330   1.70E-12  2
  1989ATK/BAU881-1097   240 - 460   2.91E-12       1330   1.70E-12  2
  1986TSA/HAM1087   300 - 2500   2.91E-12       1330      2
  1984WAR197C   300 - 1000   1.16E-11       6003      2
  1981WIN/SEM4390   273 - 410   2.82E-12       1389   1.61E-12  2
  1972WIL535-573   300 - 1000   1.66E-11       1.50E04      2
  1967BAL/JAC1676-1686   773   5.98E-12              2
 
Experiment
  2010HON/COO5718-5727   1020 - 1460   7.64E-11       2.19E04      2
  2004JIM/GIE1139-1149   298   2.00E-12           2.00E-12  2
  2004JIM/GIE1139-1149   254 - 356   2.90E-12       915   2.00E-12  2
  2003VAK/MCC10642-10647   96.00 - 296   6.80E-13       -2370      2
  1994MEL/TET473-487   298   1.74E-12           1.74E-12  2
  1992HIP/TRO333-337   1200   >1.33E-11              2
  1991TUR/VAG3244-3251   298   1.53E-12           1.53E-12  2
  1990VAG/RAV996   298   1.99E-12           1.99E-12  2
  1990LOV/MUR2386-2393   249 - 299   1.66E-12       -382   1.94E-12  2
  1990HIP/TRO1755-1760   1100   4.98E-12              2
  1989VAG/RAV7833-7837   273 - 410   2.76E-12       915   1.91E-12  2
  1983LAM/MOL4467   241 - 413   1.07E-13   2.50   -6968   1.78E-12  2
  1982TEM/WAG119   296   1.66E-12              2
  1982MAR/JOH1225   298   1.81E-12           1.81E-12  2
  1982KUR/MUR1149   250 - 370   2.91E-12       1339   1.69E-12  2
  1981WIN/SEM4390   273 - 410   3.70E-12       2162   1.55E-12  2
  1981NEL/MAR495   295   1.57E-12              2
  1980SRI/REI1286   250 - 459   2.96E-12       1364   1.70E-12  2
  1980KEY1659   245 - 423   2.51E-12       1048   1.64E-12  2
  1979HAR/PIT2581   298   6.79E-13           6.79E-13  2
  1975HAC/HOY329   298 - 670   7.97E-12       5571   8.42E-13  2
  1974HAC/HOY1236   298 - 669   7.97E-12       5571   8.42E-13  2
  1972GOR/VOL1   298   1.20E-12           1.20E-12  2
  1969TRO946   950 - 1450   7.02E-12   0.50   5014      2
  1968GRE406   300 - 458   7.02E-12   0.50   5014      2
  1967GRE2450   298   8.50E-13           8.50E-13  2
  1966GRE99   298   <5.80E-14           5.80E-14  2
  1984BAL/DEA3187   713   3.90              2
  Reference reaction:  H2 + ·OHH2O + 2
  1975MEA/HEI455   298   4.10           4.10  2
  Reference reaction:  CO + ·OHCO2 + 2
  1970BAL/WAL167-172   713   21.00              2
  Reference reaction:  CO + ·OHCO2 + 2
  1970BAL/ROS2004-2015   773   4.70              2
  Reference reaction:  H2 + ·OHH2O + 2
  1970BAL/BRA133   713 - 773   5.00              2
  Reference reaction:  H2 + ·OHH2O + 2
  1966HOA73-84   798   10.00              2
  Reference reaction:  CO + ·OHCO2 + 2
  1965HOA73   798   10.00              2
  Reference reaction:  CO + ·OHCO2 + 2
 
Theory
    2007GIN/CAM84309   250 - 500               0.00E00  2
  2005ATA/GUN502-514   298   3.00E11              2
  1989VAG/RAV7833-7837   298 - 410   1.48E-12   1.40   -457   1.78E-12  2
  1989VAG/RAV7833-7837   298 - 410   4.04E-12   2.45   416   3.41E-12  2
  1979BAL/WAL140   298 - 773   6.14E-12       4797   8.86E-13  2
  1967BAL/JAC1676-1686   773   4.70              2
  Reference reaction:  H2 + ·OHH2O + 2
  1967BAL/JAC1665-1675   733 - 813   4.70              2
  Reference reaction:  H2 + ·OHH2O + 2
  1965BAL/JAC423-433   773   4.30              2
  Reference reaction:  H2 + ·OHH2O + 2
  1964BAL/JAC423-433   773   4.70              2
  Reference reaction:  H2 + ·OHH2O + 2
  1962BAL/DOR103-109   773   7.10              2
  Reference reaction:  H2 + ·OHH2O + 2
    2003BAH/TAR229-236                       
    1995HIP/NEU3510-3516                       

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