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H2O2 + ·OH + H2O

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
Review
  1992BAU/COB411-429   300 - 1000   1.69E-11       1.50E04      2
  1986TSA/HAM1087   300 - 2500   4.00E-11       1.66E04      2
  1984WAR197C   300 - 1000   1.66E-11       1.50E04      2
  1967BAL/JAC1676-1686   733 - 803   6.91E-10       3.77E04      2
 
Experiment
  1974GOR/VOL115   298   5.71E-15           5.71E-15  2
  1970BAL/BRA133   713 - 773   8.25E-10       3.92E04      2
  1962BAL/DOR103-109   773   1.00E-14              2
  1975MEA/HEI455   298   1.30           1.30  2
  Reference reaction:  H2O2 + H2 + HO2 2
  1972GOR/VOL1   298   2.00           2.00  2
  Reference reaction:  H2O2 + H2 + HO2 2
  1970BAL/ROS2004-2015   773   265              2
  Reference reaction:  O2 + ·OH + 2
  1970BAL/BRA133   713 - 773   244       -3.04E04      2
  Reference reaction:  O2 + ·OH + 2
  1969BAL/WAL806   713   0.51              2
  Reference reaction:  C2H5CHO + H2 + CH3CH2CO 2
  1962BAL/DOR103-109   773   268              2
  Reference reaction:  O2 + ·OH + 2
 
Theory
    2006KOU/BAH149-156                      2
  1979BAL/WAL140   713 - 773   1.33E-09       3.81E04      2
  1958FOR/GIG340   700 - 740   5.33E-11       2.93E04      2
  1967BAL/JAC1676-1686   773   265              2
  Reference reaction:  O2 + ·OH + 2
  1967BAL/JAC1665-1675   733 - 813   265              2
  Reference reaction:  O2 + ·OH + 2
  1965BAL/JAC423-433   713   6.19              2
  Reference reaction:  H2O2 + H2 + HO2 2
  1964BAL/JAC423-433   713   8.09              2
  Reference reaction:  H2O2 + H2 + HO2 2

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