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O2 + ·FO2F

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
Review
  2007ATK/BAU981-1191   298   5.80E-33           5.80E-33  3
  2007ATK/BAU981-1191   100 - 380   5.87E-33   -1.70       5.87E-33  3
  1997DEM/SAN1-266   200 - 300   4.41E-33   -1.20       4.41E-33  3
  1997ATK/BAU521-1011   100 - 400   5.79E-33   -1.70       5.79E-33  3
  1994DEM/SAN   200 - 300   4.41E-33   -1.20       4.41E-33  3
  1992ATK/BAU1125-1568   300 - 400   3.69E-33   -1.00          3
  1989ATK/BAU881-1097   200 - 300   4.30E-33   -1.40       4.30E-33  3
  1981BAU/DUX   291 - 300   5.71E-33           5.71E-33  3
  2007ATK/BAU981-1191   100 - 380   1.20E-10           1.20E-10  2
  2007ATK/BAU981-1191   298   1.20E-10           1.20E-10  2
  1997ATK/BAU521-1011   100 - 400   1.20E-10           1.20E-10  2
  1989ATK/BAU881-1097   200 - 300   3.01E-11           3.01E-11  2
 
Experiment
  1995CAM/CRO5317-5326   100 - 373   4.41E-33   -1.40       4.41E-33  3
  1995CAM/CRO5317-5326   100 - 373   5.79E-33   -1.70       5.79E-33  3
  1995CAM/CRO5317-5326   100 - 373   3.69E-33   -1.10       3.69E-33  3
  1988LYM/HOL7232   298   2.81E-33           2.81E-33  3
  1988LYM/HOL7232   298   3.09E-33           3.09E-33  3
  1988LYM/HOL7232   298   1.10E-32           1.10E-32  3
  1987PAG/RAT88   295 - 359   4.52E-33   -1.60       4.52E-33  3
  1984BEZ/CHA281   110 - 300   6.04E-33   -3.00       6.04E-33  3
  1980SMI/WRI481   298   3.20E-33           3.20E-33  3
  1979SHA/KOT187   223 - 293   2.76E-34       -7525      3
  1979CHE1141   298   1.00E-32           1.00E-32  3
  1978CHE/TUP98   228 - 310   4.69E-34       -7109   8.26E-33  3
  1976ARU/POP251   293   <5.02E-33              3
  1976ARU/POP251   293   1.40E-32              3
  1976ARU/POP251   293   7.20E-33              3
  1976ARU/POP251   293   6.01E-33              3
  1995CAM/CRO5317-5326   100 - 373   1.20E-10           1.20E-10  2
  1994SEH/SEH6731-6739   298   2.71E-12           2.71E-12  2
  1994ELL/SEH287-294   295   1.91E-13              2
  1992WAL/MAR982-986   298   2.36E-13           2.36E-13  2
  1991WAL/NIE785-798   298   2.41E-13           2.41E-13  2
  1974MIL/WIL857   295   <5.00E-03              2
  Reference reaction:  C2H2 + ·F → CHF=CH· 2
  1974MIL/WIL857   295   <6.00E-03              2
  Reference reaction:  C2H4 + ·FCH2CH2F 2
 
Theory
  1988LYM/HOL7232   290 - 310   5.27E-34       -7533   1.10E-32  3
  1988LYM/HOL7232   290 - 310   1.34E-34       -7533   2.80E-33  3
  1988LYM/HOL7232   290 - 310   1.48E-34       -7533   3.10E-33  3
  1986PLU/RYA205   295   1.60E-31              3
  1983PAT/GOL1189   300   1.60E-32              3
  1986PLU/RYA205   295   3.01E-11              2

Search returned 41 records.