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Welcome
The NIST Chemical Kinetics Database includes essentially all reported kinetics
results for thermal gas-phase chemical reactions. The database is designed to
be searched for kinetics data based on the specific reactants involved, for
reactions resulting in specified products, for all the reactions of a
particular species, or for various combinations of these. In addition, the
bibliography can be searched by author name or combination of names. The
database contains in excess of 38,000 separate reaction records for over 11,700
distinct reactant pairs. These data have been abstracted from over 12,000
papers with literature coverage through early 2000.
Rate constant records for a specified reaction are found by searching the
Reaction Database. All rate constant records for that reaction are returned,
with a link to "Details" on that record.
Each rate constant record contains the following information (as available):
- Reactants and, if defined, reaction products;
- Rate parameters: A, n, Ea/R, where k = A* (T/298)**n exp[-(Ea/R)/T], where
T is the temperature in Kelvins;
- Uncertainty in A, n, and Ea/R, if reported;
- Temperature range of experiment or temperature range of validity of a
review or theoretical paper;
- Pressure range and bulk gas of the experiment;
- Data type of the record (i.e., experimental, relative rate measurement,
theoretical calculation, modeling result, etc.). If the result is a relative
rate measurement, then the reaction to which the rate is relative is also
given;
- Experimental procedure, including separate fields for the description of
the apparatus, the time resolution of the experiment, and the excitation
technique. A majority of contemporary chemical kinetics methods are
represented.
The Kinetics Database is being expanded to include other resources for the
convenience of the users. Presently this includes direct links to the
corresponding NIST WebBook page for all substances for which such a link is
possible. This is indicated by underling and highlighting the species. The
WebBook provides thermodynamic, spectral, and other data on the species. Note
that the link to the WebBook is opened as a new frame in your browser.
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